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Gibbs regeln deutsch

gibbs regeln deutsch

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The three diagrams at right correspond to octahedral coordination with a coordination number of six: The central diagram shows the minimal radius ratio.

Similar geometrical proofs yield the minimum radius ratios for the highly symmetrical cases C. An octahedron may then form with a radius ratio greater than or equal to.

If the radius ratio is less than the minimum, two anions will tend to depart and the remaining four will rearrange into a tetrahedral geometry where they are all in contact with the cation.

The radius ratio rules are a first approximation which have some success in predicting coordination numbers, but many exceptions do exist. A stable ionic structure is arranged to preserve local electroneutrality , so that the sum of the strengths of the electrostatic bonds to an anion equals the charge on that anion.

Some examples are given in the table. Pauling showed that this rule is useful in limiting the possible structures to consider for more complex crystals such as the aluminosilicate mineral orthoclase , KAlSi 3 O 8 , with three different cations.

The sharing of edges and particularly faces by two anion polyhedra decreases the stability of an ionic structure.

Sharing of corners does not decrease stability as much, so for example octahedra may share corners with one another.

The decrease in stability is due to the fact that sharing edges and faces places cations in closer proximity to each other, so that cation-cation electrostatic repulsion is increased.

The effect is largest for cations with high charge and low C. The most stable and most abundant form is rutile , in which the coordination octahedra are arranged so that each one shares only two edges and no faces with adjoining octahedra.

The other two, less stable, forms are brookite and anatase , in which each octahedron shares three and four edges respectively with adjoining octahedra.

The name Astragalus is Greek , an old name for this group of plants which were believed to have a positive effect on goat milk production.

The natural gum tragacanth is made from several species of Astragalus occurring in the Middle East , including A. Biotechnology firms are working on deriving a telomerase activator from Astragalus.

The chemical constituent cycloastragenol also called TAT2 is being studied to help combat HIV , as well as infections associated with chronic diseases or aging, [14] the National Institutes of Health states: High-quality clinical trials studies in people are generally lacking.

There is some preliminary evidence to suggest that astragalus, either alone or in combination with other herbs, may have potential benefits for the immune system, heart, and liver, and as an adjunctive therapy for cancer".

It appears to increase the production of telomerase , an enzyme that mediates the replacement of short bits of DNA known as telomeres , which play a key role in cell replication, including in cancer processes.

A proprietary extract of the dried root of A. Thus, short telomeres result in chromosome instability, and the potential for telomere lengthening as a protection against cancer is possible.

They propose that "forced" elongation of telomeres promotes the differentiation of cancer cells, probably reducing malignancy, which is strongly associated with a loss of cell differentiation.

Astragalus may interact with medications that suppress the immune system , such as cyclophosphamide.

For example, several species native to North America contain the alkaloid swainsonine , which may cause "locoism" in livestock.

Several species, including A. From Wikipedia, the free encyclopedia. This article is about the plant genus. For the ankle bone, see talus bone.

Acanthophaca Nevski Aragallus Neck. Barnebyella Podlech Batidophaca Rydb. Cryptorrhynchus Nevski Ctenophyllum Rydb. Hedyphylla Steven Hesperastragalus A.

Kiapasia Woronow ex Grossh. List of Astragalus species. Royal Botanical Gardens Kew. Retrieved 6 January Retrieved 9 December — via eFloras.

New Mexico State University. Retrieved 9 December

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The decrease in stability is due to the fact that sharing edges and faces places cations in closer proximity to each other, so that cation-cation electrostatic repulsion is increased.

The effect is largest for cations with high charge and low C. The most stable and most abundant form is rutile , in which the coordination octahedra are arranged so that each one shares only two edges and no faces with adjoining octahedra.

The other two, less stable, forms are brookite and anatase , in which each octahedron shares three and four edges respectively with adjoining octahedra.

In a crystal containing different cations, those of high valency and small coordination number tend not to share polyhedron elements with one another.

The structure contains distinct SiO 4 tetrahedra which do not share any oxygens at corners, edges or faces with each other. The number of essentially different kinds of constituents in a crystal tends to be small.

The repeating units will tend to be identical because each atom in the structure is most stable in a specific environment.

There may be two or three types of polyhedra, such as tetrahedra or octahedra, but there will not be many different types. From Wikipedia, the free encyclopedia.

The nature of the chemical bond and the structure of molecules and crystals; an introduction to modern structural chemistry 3rd ed. Inorganic Chemistry 2nd ed.

Herring, General Chemistry 8th ed. Retrieved from " https: Views Read Edit View history. This article is about the plant genus.

For the ankle bone, see talus bone. Acanthophaca Nevski Aragallus Neck. Barnebyella Podlech Batidophaca Rydb. Cryptorrhynchus Nevski Ctenophyllum Rydb.

Hedyphylla Steven Hesperastragalus A. Kiapasia Woronow ex Grossh. List of Astragalus species. Royal Botanical Gardens Kew. Retrieved 6 January Retrieved 9 December — via eFloras.

New Mexico State University. Retrieved 9 December International Plant Names Index. Retrieved 10 December Flora of the Chicago Region: A Floristic and Ecological Synthesis.

Indiana Academy of Sciences. Plants for a Future. Retrieved 24 December Tehran University Publications ; pp.

Retrieved January 28, The Journal of Immunology. Telomeres and Telomerase in Cancer. Retrieved from " https: Views Read Edit View history.

In other projects Wikimedia Commons Wikispecies.

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